Highly concentrated emulsions as novel reaction media |
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| Institution: | 1. Instituto de Química Avanzada de Cataluña, Consejo Superior de Investigaciones Científicas (IQAC-CSIC), CIBER de Bioingeniería, Biomateriales y Nanomedicina (CIBER-BBN), Jordi Girona 18-26, 08034 Barcelona, Spain;3. Department of Chemical Engineering & Analytical Science, University of Manchester, Manchester M60 1QD, United Kingdom |
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| Abstract: | Synthesis of a cationic surfactant, Nα-lauroyl arginine methyl ester hydrochloride (LAM) has been carried out in gel emulsions of the system water/C14E4/decane. The yields of LAM synthesized in gel emulsions are comparable to those obtained in conventional dimethylformamide (DMF) media. The rate of LAM formation is faster in gel emulsions at short times, the reaction taking place without mechanical energy input and at 25°C. |
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