| 邻苯二甲酸异丙酯酰氧基-丙烯酰氧基-乙酰乙酸乙酯络铝及其聚合物的合成与荧光性质 |
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| 引用本文： | 章永化,章文贡.邻苯二甲酸异丙酯酰氧基-丙烯酰氧基-乙酰乙酸乙酯络铝及其聚合物的合成与荧光性质[J].高等学校化学学报,1992,13(3):404. |
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| 作者姓名： | 章永化 章文贡 |
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| 作者单位： | 福建师范大学高分子研究所, 福州, 350007 |
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| 摘 要： | 通过异丙氧基铝和邻苯二甲酸酐、乙酰乙酸乙酯及丙烯酸反应,合成了螯合物单体邻苯二甲酸异丙酯酰氧基-丙烯酰氧基-乙酰乙酸乙酯络铝,由自由基聚合法合成了聚合物,用元素分析仪、VPO、IR、1HNMR和27AlNMR证实了它们的结构,并研究了它们在DMF中的荧光性质。
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| 关 键 词： | 邻苯二甲酸异丙酯酰氧基-丙烯酰氧基-乙酰乙酸乙酯络铝 聚合 结构表征 荧光性质 |
| 收稿时间： | 1991-02-08 |
Studies on Synthesis and Fluorescent Property of Aluminium Isopropyl Phthalate Acryloxyl Ethyl acetoacetate and Its Polymer |
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| ZHANG Yong-hua,ZHANG Wen-gong.Studies on Synthesis and Fluorescent Property of Aluminium Isopropyl Phthalate Acryloxyl Ethyl acetoacetate and Its Polymer[J].Chemical Research In Chinese Universities,1992,13(3):404. |
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| Authors: | ZHANG Yong-hua ZHANG Wen-gong |
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| Institution: | Institute of Polymer Science, Fujian Normal University, Fuzhou, 350007 |
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| Abstract: | Chelate compound aluminium isopropyl phthalate acryloxyl ethylacetoacetate (AIPAE) has been synthesized by the reaction of aluminium triisopropoxide with phthalic anhydride, ethylacetoacetate and acrylic acid. Chelate polymer PAIPAE has been synthesized by radical polymerization of AIPAE. The structures of AIPAE and PAIPAE have been determinated by elemental analyzer, ICP, IR, 1H NMR and 27Al NMR. Their fluorescent property in DMF has mainly been studied. |
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| Keywords: | Aluminium isopropyl phthalate acryloxyl ethylacetoacetate Polymerization Structure characterization Fluorescent property |
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