Diastereoselective reduction of cyclopropenylcarbinol: new access to anti-cyclopropylcarbinol derivatives |
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| Authors: | Zohar Elinor Marek Ilan |
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| Institution: | Department of Chemistry and Institute of Catalysis Science and Technology, Technion-Israel Institute of Technology, Technion City, Haifa 32000, Israel. |
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| Abstract: | reaction: see text] Cyclopropenylcarbinol derivatives are regio- and diastereoselectively reduced with LiAlH(4) in Et(2)O into trans-cyclopropylcarbinols as a single isomer. The regioselectivity of the hydroalumination reaction on the cyclopropenyl ring has been mapped out by deuterium labeling experiments. |
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