Total synthesis of carbazoquinocin C: application of the o-benzannulation of Fischer carbene complexes to carbazole-3,4-quinone alkaloids |
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Authors: | Rawat Manish Wulff William D |
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Affiliation: | Department of Chemistry, Michigan State University, East Lansing, Michigan 48824, USA. |
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Abstract: | [reaction: see text] The photoinduced o-benzannulation of 3-(2-vinyl)indolylcarbene complexes provides a direct route to carbazole derivatives that are oxygenated in the 3- and 4-positions. This reaction is quite efficient and provides for a unique synthesis of the lipid peroxidation inhibitor carbazoquinocin C. |
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