Synthesis,Crystal Structure and Luminescence of a New Zn(Ⅱ) Complex [Zn(1,2,3-HBTC)(L)]_2 Constructed by Mixed Ligands

A new Zn(Ⅱ) complex,[Zn(1,2,3-HBTC)(L)]2(1,L = 2-(2-chloro-6-fluorophenyl)-1H-imidazo[4,5-f][1,10]phenanthroline and 1,2,3-H3 BTC = 1,2,3-benzentricarboxylic acid),was synthesized under hydrothermal conditions and characterized by single-crystal X-ray diffraction.It crystallizes in triclinic,space group P1 with a = 10.455(2),b = 11.533(2),c = 12.499(3) ?,α = 116.97(3),β = 94.08(3),γ = 103.29(3)o,V = 1280.2(4) ?3,Z = 1,C56H28Cl2F2N8O12Zn2,Mr = 1244.50,Dc = 1.614 g/cm3,F(000) = 628,μ(Mo Ka) = 1.124 mm-1,R = 0.0502 and w R = 0.1417.In compound 1,two 1,2,3-HBTC anions bridge two Zn(Ⅱ) atoms to give a dimeric structure with Zn···Zn distance of 3.15 ?.Adjacent dimers interact through π-π stackings between two L ligands to result in a supramolecular layer.Moreover,N–H···O and O–H···N hydrogen bonds further stabilize the 2D supramolecular architecture of 1.In addition,the luminescent property of 1 has been studied.