| One-dimensional Hydrogen-bonded Polymer Based on Tetra-iso-butyl-resorcin[4]arene and 2,6-Diacetylpyridine |
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| 引用本文： | 刘书群,姚文锐,张千峰. One-dimensional Hydrogen-bonded Polymer Based on Tetra-iso-butyl-resorcin[4]arene and 2,6-Diacetylpyridine[J]. 结构化学, 2005, 24(1): 99-103 |
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| 作者姓名： | 刘书群 姚文锐 张千峰 |
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| 作者单位： | Department of Applied Chemistry，School of Chemical Engineering and Chemistry，Anhui University of Technology，Maanshan，Anhui 243002，China |
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| 基金项目： | This project was supported by the Key Scientific Research Foundation of State Education Ministry of China (No. 204067) |
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| 摘 要： | 1INTRODUCTIONResorcin[4]arenesarecavity-shapedmacro-cycleswhichcanbeeasilysynthesizedfromresor-cinolandaldehydesinthepresenceofacidiccataly-sis[1].Theyareattachedmuchinterestinthefieldofsupramolecularchemistryasartificialreceptorsandstartingmaterialsforthepreparationofmoresophis-ticatedmolecules[2].Duetotheirstructuralfeaturestheyplayanimportantroleashostmoleculesforavarietyofneutralandchargedguestcompounds[3].Theresorcin[4]arenesusuallyadoptfourdifferentcon-formers,crown(rccc,C4),boat(rc…
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| 关 键 词： | 一维空间氢键聚合物 四异丁基-间笨二酚[4]芳烃 超分子化学 2,6-二乙酰吡啶 |
One-dimensional Hydrogen-bonded Polymer Based on Tetra-iso-butyl-resorcin[4]arene and 2,6-Diacetylpyridine |
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| LIU Shu-Qun,YAO Wen-Rui,ZHANG Qian-feng. One-dimensional Hydrogen-bonded Polymer Based on Tetra-iso-butyl-resorcin[4]arene and 2,6-Diacetylpyridine[J]. Chinese Journal of Structural Chemistry, 2005, 24(1): 99-103 |
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| Authors: | LIU Shu-Qun YAO Wen-Rui ZHANG Qian-feng |
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| Abstract: | Two adjacent double-stranded arrays as well as linear and zigzag chains generated from 2,6-ac2py and water bridging two tetra-iso-butyl-resorcin[4] arene molecules, respectively, facilitate self-inclusion of a one-dimensional hydrogen-bonded polymer. |
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| Keywords: | resorcinarene hydrogen-bonding supramolecular chemistry |
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