| Reactions of enamines with fluorinated acyl chlorides----Synthesis of fluorinated 1,3-diketones and 1,3-keto-aldehydes |
| |
| 作者姓名： | 贺海鹰 曲延玲 赵成学 |
| |
| 作者单位： | College of Chemistry and Chemical Technology，Shanghai Jiaotong University，800 Dongchuan Lu，Shanghai 200240，China，College of Chemistry and Chemical Technology，Shanghai Jiaotong University，800 Dongchuan Lu，Shanghai 200240，China，College of Chemistry and Chemical Technology，Shanghai Jiaotong University，800 Dongchuan Lu，Shanghai 200240，China |
| |
| 基金项目： | Project (No. 29272043) supported by the National Natural Science Foundation of China |
| |
| 摘 要： | The reactions of enamines (1a-b,4,6) with fluorinated acyl chlorides (2a-d) produced fluorinated 1,3-diketones (3a-f) and 1,3-keto-aldehydes (7a-c) in good yields as well as byproducts fluorinated acylamides (5a-c).It is proposed that the reactions involve nucleophilic attack by the C-atora and/or N-atom of the enamines on acyl carbon of the fluorinated acyl chlorides.
|
Reactions of enamines with fluorinated acyl chlorides----Synthesis of fluorinated 1,3-diketones and 1,3-keto-aldehydes |
| |
| HE,Hai-Ying QU,Yan-Ling ZHAO,Cheng-XueCollege of Chemistry and Chemical Technology,Shanghai Jiaotong University, Dongchuan Lu,Shanghai ,China.Reactions of enamines with fluorinated acyl chlorides----Synthesis of fluorinated 1,3-diketones and 1,3-keto-aldehydes[J].Chinese Journal of Chemistry,1998,16(6):549-556. |
| |
| Authors: | HE Hai-Ying QU Yan-Ling ZHAO Cheng-XueCollege of Chemistry and Chemical Technology Shanghai Jiaotong University Dongchuan Lu Shanghai China |
| |
| Institution: | HE,Hai-Ying QU,Yan-Ling ZHAO,Cheng-XueCollege of Chemistry and Chemical Technology,Shanghai Jiaotong University,800 Dongchuan Lu,Shanghai 200240,China |
| |
| Abstract: | The reactions of enamines (1a-b,4,6) with fluorinated acyl chlorides (2a-d) produced fluorinated 1,3-diketones (3a-f) and 1,3-keto-aldehydes (7a-c) in good yields as well as byproducts fluorinated acylamides (5a-c).It is proposed that the reactions involve nucleophilic attack by the C-atora and/or N-atom of the enamines on acyl carbon of the fluorinated acyl chlorides. |
| |
| Keywords: | Fluorinated 1 3-dicarbonyl compounds enamine fluorinated acyl chloride nucle-ophilic reaction |
| 本文献已被 CNKI 等数据库收录！ |
|
