Influence of substituents on rate constants for recombination of secondary and primary peroxy radicals |
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| Authors: | S. L. Khursan and V. S. Martemyanov |
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| Affiliation: | (1) State University, 450074 Ufa, USSR |
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| Abstract: | A linear correlation has been found between the logarithm of rate constants (2kt) for the recombination of secondary peroxy radicals (ROO ) and the   constants of substituents, R:1g 2kt=(6.84±0.03)+(2.60±0.10) . Rate constant for the recombination of primary peroxy radicals proves to be independent of the substituent nature: 1g 2kt=8.5±0.4.
                      (2kt)     (ROO)  R: 1g 2kt=(6,84±0,03)+(2,60±0,10) .  , 1g 2kt=8,5±0,4.
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