Kinetics of reactions of chlorine atom/arene complexes withn-heptane |
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| Institution: | (1) Central Research Institute for Chemistry, Hungarian Academy of Sciences, P.O. Box 17, H-1525 Budapest, Hungary |
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| Abstract: | Room temperature rate constants have been determined for reactions ofn-hepatane with Cl/benzene (k=6×107 dm3 mol−1 s−1), Cl/toluene (k=1×107 dm3 mol−1 s−1) and Cl/m-xylene (k=1.7×106 dm3 mol−1 s−1) complexes, respectively, in carbon tetrachloride, using the laser flash photolysis of nitrogen trichloride as a chlorine
atom source. |
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| Keywords: | Reactivity of chlorine atom-arene complexes complex regeneration laser flash photolysis |
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