| STRUCTURE OF MOLECULAR COMPOUND CRYSTAL A_2B(A =1, 6, 7, 8,-TETRA-PHENYL (3, 4-BENZO)BICYCLO[4, 2, 0]OCTA-7-ENE, B=CIS, CIS-1,2,3,4,-TETRAPHENYLBUTADIENE) |
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| 作者姓名： | Huan Zhen-Wei Yao Xin-Kan Wang Ru-Ji Wang Hong-Gen Liu Wei-Guo |
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| 作者单位： | Huan Zhen-Wei Yao Xin-Kan Wang Ru-Ji Wang Hong-Gen Liu Wei-Guo Department of Chemistry and Central Laboratory，Nankai University，Tianjin，300071 |
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| 基金项目： | The Project was supported by the National Science Foundation of China |
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| 摘 要： | <正> C100H78, (A: C36H28, B: C28H22) Mr = 1279. 74, monoclinic, P21/a, a=17. 282(3), b=10. 669(4), c= 19, 927(3) A , β =102. 99(1)°,V = 3580. 1(2) A3, Z=2, μ(MoKα) = 0. 623cm-1, F(000) = 1356, Dc=1. 187g/cm3, room temperature. The final R=0. 084, Rw = 0. 086 for 1255 independent observed reflections (I≥3σ(I)). Owing to the existence of 1,6,7, 8-Tetraphenyl (3,4-benzo)-bicyclo4, 2, 0]octa-7-ene(A) , cis, cts-1, 2, 3, 4-Tetraphenylbutadiene (B) in A2B can take the different conformation from the one in the pure B crystal. The reason of the formation of this molecular compound crystal is put forward.
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STRUCTURE OF MOLECULAR COMPOUND CRYSTAL A_2B(A =1, 6, 7, 8,-TETRA-PHENYL (3, 4-BENZO)BICYCLO[4, 2, 0]OCTA-7-ENE, B=CIS, CIS-1,2,3,4,-TETRAPHENYLBUTADIENE) |
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| Huan Zhen-Wei Yao Xin-Kan Wang Ru-Ji Wang Hong-Gen Liu Wei-Guo.STRUCTURE OF MOLECULAR COMPOUND CRYSTAL A_2B(A =1, 6, 7, 8,-TETRA-PHENYL (3, 4-BENZO)BICYCLO[4, 2, 0]OCTA-7-ENE, B=CIS, CIS-1,2,3,4,-TETRAPHENYLBUTADIENE)[J].Chinese Journal of Structural Chemistry,1993(5). |
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| Authors: | Huan Zhen-Wei Yao Xin-Kan Wang Ru-Ji Wang Hong-Gen Liu Wei-Guo |
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| Institution: | Huan Zhen-Wei Yao Xin-Kan Wang Ru-Ji Wang Hong-Gen Liu Wei-Guo Department of Chemistry and Central Laboratory,Nankai University,Tianjin,300071 |
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| Abstract: | C100H78, (A: C36H28, B: C28H22) Mr = 1279. 74, monoclinic, P21/a, a=17. 282(3), b=10. 669(4), c= 19, 927(3) A , β =102. 99(1)°,V = 3580. 1(2) A3, Z=2, μ(MoKα) = 0. 623cm-1, F(000) = 1356, Dc=1. 187g/cm3, room temperature. The final R=0. 084, Rw = 0. 086 for 1255 independent observed reflections (I≥3σ(I)). Owing to the existence of 1,6,7, 8-Tetraphenyl (3,4-benzo)-bicyclo4, 2, 0]octa-7-ene(A) , cis, cts-1, 2, 3, 4-Tetraphenylbutadiene (B) in A2B can take the different conformation from the one in the pure B crystal. The reason of the formation of this molecular compound crystal is put forward. |
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| Keywords: | Crystal Structure Molecular Compound A2B Type |
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