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Performance of ionic liquid as catalyst in the copolymerization of phenyl glycidyl ether with carbon dioxide |
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| Authors: | Dae-Won Park Na-Young Mun Eun-Ha Lee Youngson Choe Sang-Wook Park |
| Affiliation: | (1) Laboratoire de Chimie des Matériaux et Catalyse, Département de Chimie, Faculté des Sciences de Tunis, Campus Universitaire, 2092 Tunis, Tunisia;(2) Laboratoire de Chimie des Matériaux et Catalyse, Département de Chimie, Faculté des Sciences de Tunis, Campus Universitaire, 2092 Tunis, Tunisia;(3) Laboratoire de Chimie des Matériaux et Catalyse, Département de Chimie, Faculté des Sciences de Tunis, Campus Universitaire, 2092 Tunis, Tunisia |
| Abstract: | Summary Selective ammoxidation of ethylene over Co-ZSM-5 prepared by aqueous and solid-state ion exchange has been studied. The catalyst prepared using solid-state exchange showed higher activity and selectivity to acetonitrile. Catalysts tested in the ammoxidation of ethylene were previously characterized by chemical analysis, XRD, N2-BET measurements and FTIR. TPD of ammonia and FTIR of pyridine used as probe molecule showed that solid-state ion exchange of H-ZSM-5 with cobalt generates new Lewis acid sites which seem to play a role in the ammoxidation reaction. |
| Keywords: | ethylene Co-ZSM-5 solid-state exchange Ammoxidation |
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