Reaction of unsaturated compounds with ethyl benzenesulfenate and trimethylsilyl isothiocyanate |
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| Authors: | N. V. Zyk A. Yu. Gavrilova O. A. Mukhina A. A. Borisenko O. B. Bondarenko N. S. Zefirov |
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| Affiliation: | 1. Department of Chemistry, M. V. Lomonosov Moscow State University, 1 Leninskie Gory, 119992, Moscow, Russian Federation
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| Abstract: | A new method for the synthesis of thiocyanato- and isothiocyanatoalkyl phenyl sulfides by the reaction of unsaturated compounds with ethyl benzenesulfenate and trimethylsilyl isothiocyanate has been suggested. Regio- and stereoselectivity of the reaction was studied, having taken alkenes, dienes, and alkynes as examples. |
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