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[4+2] Cycloaddition reactions of 1,2,4,5-tetrazines with allylcarboranes
Authors:G. L. Rusinov  R. I. Ishmetova  S. G. Tolshchina  N. K. Ignatenko  I. N. Ganebnykh  P. A. Slepukhin  V. A. Ol’shevskaya  V. N. Kalinin  V. N. Charushin
Affiliation:1. I. Ya. Postovsky Institute of Organic Synthesis, Ural Branch of the Russian Academy of Sciences, 22 ul. S. Kovalevskoi, 620990, Ekaterinburg, Russian Federation
2. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 28 ul. Vavilova, 119991, Moscow, Russian Federation
Abstract:The [4+2] cycloaddition reactions of 3,6-disubstituted 1,2,4,5-tetrazines with 9-allyl-1,7-,9-allyl-1,2-dicarba-closo-dodecaboranes and 1-allyl-2-isopropyl-1,2-dicarba-closo-dodecab-orane have been studied. The pyridazines containing carborane cage have been synthesized for the first time.
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