| O—芳基苯基硫代膦酰肼与异（硫）氰酸酯的加成反应 |
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| 引用本文： | 金桂玉,沙跃武.O—芳基苯基硫代膦酰肼与异（硫）氰酸酯的加成反应[J].高等学校化学学报,1989,10(2):158-163. |
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| 作者姓名： | 金桂玉 沙跃武 |
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| 作者单位： | 南开大学元素有机化学研究所
(金桂玉，沙跃武，蔡建平，陈茹玉)，天津师范大学化学系
(缪方明)，天津师范大学化学系(刘小兰) |
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| 摘 要： | 合成了一些新的硫代膦酰基-及N,N′-双(硫代膦酰基)氨基硫脲。分离并采用IR、~1H NMR、MS及X衍射确证了N,N′-双硫代膦酰基]氨基硫脲中是由2个手性磷原子而形成的非对映异构体。讨论了单取代和双取代氨基硫脲的质谱。
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| 关 键 词： | 硫代磷酰肼 异硫氰酸酯 加成 |
Addition Reaction of Aryloxyphenylthiophosphonyl Hydrazides with Iso(thio)cyanates |
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| Jin Guiyu,Sha Yuewu,Cai Jianping,Chen Ruyu.Addition Reaction of Aryloxyphenylthiophosphonyl Hydrazides with Iso(thio)cyanates[J].Chemical Research In Chinese Universities,1989,10(2):158-163. |
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| Authors: | Jin Guiyu Sha Yuewu Cai Jianping Chen Ruyu |
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| Abstract: | Some new N-thionophosphonyl- and N,N' -bis(thionophosphonyl) thio-semicarbazides were synthesized.The diastereoisomers of N,N'-(thionophosphonyl) thiosemicarbazides possessing two chiral P-atoms were separated and their structures were determined by IR, 1H NMR, MS spectra, elemental analysis and X-ray diffraction method. The MS spectra of mono- and disubstituted thiophosphonyla-minourea were discussed. |
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| Keywords: | Thionophosphonyl hydrazide Iso(thio) cyanate Addition Thiono- phosphonylthiosemicarbazide |
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