Self-assembly of a bis-porphyrinic supramolecular rectangle using two orthogonal binding strategies |
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Authors: | Kishore Ravuri S K Kalsani Venkateshwarlu Schmittel Michael |
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Institution: | Center of Micro and Nanochemistry and Engineering, Organische Chemie I, Universit?t Siegen, Adolf-Reichwein-Str., D-57068 Siegen, Germany. |
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Abstract: | A bis-porphyrinic rectangle is created via a double self-assembly algorithm using two orthogonal coordination themes, i.e. first a 90 degrees building block composed of a dynamic heteroleptic Cu(I) or Ag(I) bisphenanthroline followed by a coordinative dimerization using the pyridine-zinc porphyrin motif; the spectroscopic and electrochemical properties as well as the dynamic nature of the supramolecule were tested. |
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