| 1，4-苯二硫乙酸配体构筑的锌(Ⅱ)及镉(Ⅱ)配合物的合成、晶体结构及荧光性质 |
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| 引用本文： | 李伟琦,王晓娟,尹建玲,冯云龙. 1，4-苯二硫乙酸配体构筑的锌(Ⅱ)及镉(Ⅱ)配合物的合成、晶体结构及荧光性质[J]. 无机化学学报, 2012, 28(3): 613-618 |
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| 作者姓名： | 李伟琦 王晓娟 尹建玲 冯云龙 |
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| 作者单位： | 1. 浙江师范大学物理化学研究所,浙江省固体表面反应化学重点实验室,金华 321004;金华广播电视大学,金华321022
2. 浙江师范大学物理化学研究所,浙江省固体表面反应化学重点实验室,金华 321004 |
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| 基金项目： | 浙江广播电视大学重点课题(No.XKT-11Z13);浙江省教育厅科研项目(No.Y201119396)资助项目 |
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| 摘 要： | 基于1,4-苯二硫乙酸(H2L)及中性含氮配体,水热法合成了两个新的d10金属配合物[ZnClL0.5(bpp)](1)和[Cd2L(phen)4(H2O)2].L.2.78H2O(2)(bpp=1,3-di(4-pyridyl)propane,phen=1,10-phenanthroline),并通过单晶X-射线衍射、元素分析、红外光谱和热重对其结构进行了表征。结构分析表明,在配合物1中,Zn(Ⅱ)呈现四配位的扭曲四面体构型,进一步连接形成一维双链状结构。在配合物2中,Cd(Ⅱ)呈现六配位的扭曲八面体构型,并通过可能存在的氢键及π-π堆积作用,形成最终的三维超分子结构。同时,讨论了两种配合物的固体荧光性质。
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| 关 键 词： | 锌配合物 镉配合物 1,4-苯二硫乙酸 晶体结构 荧光性质 |
Synthesis, Structure, and Luminescent Property of Zinc(H) and Cadmium(H) Complex Assembled by 1,4-Benzenebis(thioacetic acid) |
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| LI Wei-Qi,WANG Xiao-Juan,YIN Jian-Ling and FENG Yun-Long. Synthesis, Structure, and Luminescent Property of Zinc(H) and Cadmium(H) Complex Assembled by 1,4-Benzenebis(thioacetic acid)[J]. Chinese Journal of Inorganic Chemistry, 2012, 28(3): 613-618 |
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| Authors: | LI Wei-Qi WANG Xiao-Juan YIN Jian-Ling FENG Yun-Long |
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| Affiliation: | Zhejiang Key Laboratory for Reactive Chemistry on Solid Surfaces, Institute of Physical Chemistry, Zhejiang Normal University, Jinhua, Zhejiang 321004, China; Jinhua Radio and Television University, Jinhua, Zhejiang 321022, China,Zhejiang Key Laboratory for Reactive Chemistry on Solid Surfaces, Institute of Physical Chemistry, Zhejiang Normal University, Jinhua, Zhejiang 321004, China,Zhejiang Key Laboratory for Reactive Chemistry on Solid Surfaces, Institute of Physical Chemistry, Zhejiang Normal University, Jinhua, Zhejiang 321004, China and Zhejiang Key Laboratory for Reactive Chemistry on Solid Surfaces, Institute of Physical Chemistry, Zhejiang Normal University, Jinhua, Zhejiang 321004, China |
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| Abstract: | Two d10 complexes assembled by 1,4-benzenebis(thioacetic acid)(H2L) and neutral N-based ligands,[ZnClL0.5(bpp)](1) and [Cd2L(phen)4(H2O)2]·L·2.78H2O(2)(bpp=1,3-di(4-pyridyl)propane,phen=1,10-phenan-throline),have been hydrothermally synthesized and characterized by single crystal X-ray diffraction,elemental analysis,IR spectroscopy,and TG analysis.In complex 1,Zn(Ⅱ) ion is four-coordinated in a distorted tetrahedron coordination environment and is further linked to a one-dimensional(1D) double chain structure.In complex 2,Cd(Ⅱ) ion is six-coordinated in a distorted octahedral coordination environment,and is linked by possible hydrogen bonds and π-π interactions to form a 3D supramolecular structure.The luminescent property in solid state of the two complexes was also studied and discussed.CCDC: 734944,1;819445,2. |
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| Keywords: | zinc complex cadmium complex 1,4-benzenebis(thioacetic acid) crystal structure luminescent property |
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