| 环氧化合物羰基化反应研究新进展 |
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| 引用本文： | 樊启佳,刘建华,陈静,夏春谷.环氧化合物羰基化反应研究新进展[J].催化学报,2012(9):1435-1447. |
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| 作者姓名： | 樊启佳 刘建华 陈静 夏春谷 |
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| 作者单位： | 中国科学院兰州化学物理研究所羰基合成与选择氧化国家重点实验室;兰州大学化学化工学院 |
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| 基金项目： | 国家自然科学基金(21073209,21133011);国家“十二五”科技支撑计划(2011BAE05B02)~~ |
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| 摘 要： | 通过催化的方法在有机化合物分子中引入羰基和其它基团而成为含氧化合物的羰基化反应,具有"原子经济性"反应的高选择性和对环境的友好性,可充分利用资源和保护环境,符合绿色化学发展趋势等优点,备受学术界及工业界青睐.综述了近年来羰基钴金属化合物催化的环氧化合物和一氧化碳羰基化反应研究的新进展,涉及的反应类型主要包括羰基化扩环、羰基化开环共聚以及羰基化开环,讨论了不同类型反应的相关机理,并展望了该领域的研究前景.
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| 关 键 词： | 环氧化合物 羰基化扩环 羰基化开环共聚 羰基化开环 反应机理 |
Recent Progress in Carbonylation of Epoxides |
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| FAN Qijia,LIU Jianhua,CHEN Jing,XIA Chungu.Recent Progress in Carbonylation of Epoxides[J].Chinese Journal of Catalysis,2012(9):1435-1447. |
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| Authors: | FAN Qijia LIU Jianhua CHEN Jing XIA Chungu |
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| Institution: | 1 State Key Laboratory for Oxo Synthesis and Selective Oxidation,Lanzhou Institute of Chemical Physics,Chinese Academy of Sciences,Lanzhou 730000,Gansu,China 2 College of Chemistry and Chemical Engineering,Lanzhou University,Lanzhou 730000,Gansu,China |
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| Abstract: | Carbonylation reactions that introduce carbonyl moiety into organic and inorganic substrates have the advantages of atom economical selectivity and environmental benignancy.Recently,it has been one of the challenging and attractive subjects in the field of value-added utilization of C1 resources and a bridge between petrochemical industry and C1 chemistry.The important transformation has drawn considerable attention from both academia and industry.We aim to present recent progress in cobalt carbonyl complexes catalyzed carbonylation of epoxides,including ring-expansion carbonylation,ring-opening carbonylative copolymerization,and ring-opening carbonylation.The development prospects are also discussed. |
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| Keywords: | epoxide ring-expansion carbonylation ring-opening carbonylative copolymerization ring-opening carbonylation reaction mechanism |
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