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Group-selective hydroalumination: a novel route to stereogenic tert-alcohol centers
Authors:Ohmori K  Suzuki T  Taya K  Tanabe D  Ohta T  Suzuki K
Institution:Department of Chemistry, Tokyo Institute of Technology, and CREST, Japan Science and Technology Corporation, O-okayama, Meguro-ku, Tokyo 152-8551, Japan.
Abstract:reaction: see text]. A new group-selective reaction is described, that is, the hydroalumination of bis-alkynyl alcohols armed with an adjacent stereogenic center, giving stereo-defined tert-alcohols of potential utility in natural product synthesis.
Keywords:
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