Group-selective hydroalumination: a novel route to stereogenic tert-alcohol centers |
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Authors: | Ohmori K Suzuki T Taya K Tanabe D Ohta T Suzuki K |
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Institution: | Department of Chemistry, Tokyo Institute of Technology, and CREST, Japan Science and Technology Corporation, O-okayama, Meguro-ku, Tokyo 152-8551, Japan. |
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Abstract: | reaction: see text]. A new group-selective reaction is described, that is, the hydroalumination of bis-alkynyl alcohols armed with an adjacent stereogenic center, giving stereo-defined tert-alcohols of potential utility in natural product synthesis. |
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