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Synthesis and characterization of phosphate-modified LiMn2O4 cathode materials for Li-ion battery
Authors:Qing Lai Jiang  Ke Du  Yan Bing Cao  Zhong Dong Peng  Guo Rong Hu  Ye Xiang Liu
Affiliation:School of Metallurgical Science and Engineering, Central South University, Changsha 410083, China
Abstract:LiMn2O4 spinel cathode materials were modified with 2 w% Li-M-PO4 (M=Co, Ni, Mn) by polyol synthesis method. The phosphate surface-modified LiMn2O4 cathode materials were physically characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM) and energy dispersive X-ray spectroscopy (EDS). The charge-discharge test showed that the cycling and rate capacities of LiMn2O4 cathode materials were significantly enhanced by stabilizing the electrode surface with phosphate.
Keywords:Li-ion battery  Cathode materials  2O4zz')"   href="  #"  > Spinel LiMn2O4  Phosphate  Polyol synthesis method
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