Gradient doping simulation of perovskite solar cells with CH3NH3Sn1−xPbxI3 as the absorber layer |
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Affiliation: | 1. Hunan Key Laboratory for Micro-Nano Energy Materials and Devices, Xiangtan University, Hunan, 411105, PR China;2. Laboratory for Quantum Engineering and Micro-Nano Energy Technology and Faculty of Materials and Optoelectronic Physics, Xiangtan University, Hunan, 411105, PR China;3. College of Chemistry, Xiangtan University, Hunan, 411105, PR China |
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Abstract: | In this study, we built a perovskite solar cells(PSCs) model with a Au/CuSCN/CH3NH3Sn1−xPbxI3/TiO2/FTO glass structure using the SCAPS program and use polynomial fitting to obtain the relationship between the conduction/valence bands of CH3NH3Sn1−xPbxI3 and the x value, which is more complex and accurate than that in any previous research. The influences of thickness, electron and hole mobilities, relative permittivity, effective conduction band density, effective valence band density, and the value of x on the solar cell performance are analyzed. Furthermore, we simulate the situation where the doping concentration changes with the absorption layer depth of the device and a special bandgap is formed. The power conversion efficiency of the device improves from 19.96% to 20.52%, with an open-circuit voltage of 0.776 V, a short-circuit current of 33.79 mA/cm2, and a filling factor of 77.39% when double gradient doping is performed. The application value of gradient doping in the device absorption layer is obtained. |
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Keywords: | Perovskite solar cells Absorption layer Graded doping |
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