Photoactive organic-inorganic hybrid materials: From silylated compounds to optical applications |
| |
| Affiliation: | 1. Department of Chemistry, North Carolina State University, Raleigh, NC 27695-8204, USA;2. Department of Chemistry, University of California, Riverside, CA 92521-0403, USA;3. Department of Chemistry, Washington University, St. Louis, MO 63130-4889, USA;1. Laboratory of Theoretical and Computational Nanoscience, CAS Center for Excellence in Nanoscience, National Center for Nanoscience and Technology, Chinese Academy of Sciences, No.11 ZhongGuanCun BeiYiTiao, Beijing 100190, China;2. Element Strategy Initiative for Catalysts and Batteries, Kyoto University, Goryo-Ohara 1-30, Nishikyo-ku, Kyoto 615-8245, Japan;1. Instituto de Química, Universidade Federal do Rio Grande do Sul, Av. Bento Gonçalves, 9500, Campus do Vale, 91501-970 Porto Alegre, RS, Brazil;2. Departamento de Química, Universidade de Coimbra, Rua Larga s/n, 3004-535 Coimbra, Portugal;3. Departamento de Química, Laboratório de Bioinorgânica e Materiais Porfirínicos, Universidade Federal de Santa Maria, 97105-900 Santa Maria, RS, Brazil |
| |
| Abstract: | This review summarizes several aspects of type II photoactive organic-inorganic hybrid materials prepared from silylated fluorophores, including their photophysical properties and uses. In this sense, several examples are presented and discussed taking the nature of the silyl derivative into account. Applications as latent fingerprints detection, chemosensors for metal cations, anions, pH, heavy metals, and small organic molecules, as well as recent use as drug delivery systems, bioimaging, organic solar cells, aerogels, and highly fluorescent hybrid materials, are reported and compared to the literature. Also, fluorescent type II organic-inorganic hybrid materials from non-silylated fluorophores, prepared with binding agents, such as 3-(triethoxysilyl)propyl isocyanate (TESPIC), 3-mercaptopropyltriethoxysilane (TMMPS), or 3-isocyanato propyltrimethoxysilane (ICPTES) are also covered in this review. |
| |
| Keywords: | Silsesquioxanes Hybrid materials Fluorescent materials Ormosil Optical sensors Bioimaging |
| 本文献已被 ScienceDirect 等数据库收录！ |
|
