| Synthesis and properties of novel aliphatic polycarbonate from carbon dioxide with 1,2-butylene oxide and ε-caprolactone |
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| 作者姓名： | Yan Fei Liu Ke Long Huang Dong Ming Peng Su Qin Liu Hong Wu Institute of Functional Materials and Chemistry Central South University Changsha China |
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| 作者单位： | Yan Fei Liu，Ke Long Huang，Dong Ming Peng，Su Qin Liu，Hong Wu Institute of Functional Materials and Chemistry，Central South University，Changsha 410083，China |
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| 基金项目： | This work was financially supported by the National High Technology and Development Research 863 Program of China (No. 2001 AA218011) and Outstanding Young Researcher Foundation of Hunan Province (No. 06BB002). |
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| 摘 要： | A new degradable aliphatic poly(butylene-co-e-caprolactone carbonate) (PBCL) was synthesized through the terpolymerization of carbon dioxide, 1,2-butylene oxide (BO) and e-caprolactone (CL), a polymer supported bimetallic complex (PBM) was used as a catalyst. The terpolymers prepared were characterized by FT-IR,1H NMR, 13C NMR, WXRD and DSC. The hydrolysis tests were carried out to appraise the degradability of the copolymers.
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| 收稿时间： | 8 June 2006 |
Synthesis and properties of novel aliphatic polycarbonate from carbon dioxide with 1,2-butylene oxide and ?-caprolactone |
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| Yan Fei Liu,Ke Long Huang,Dong Ming Peng,Su Qin Liu,Hong Wu Institute of Functional Materials and Chemistry,Central South University,Changsha ,China.Synthesis and properties of novel aliphatic polycarbonate from carbon dioxide with 1,2-butylene oxide and ?-caprolactone[J].Chinese Chemical Letters,2007,18(2):209-212. |
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| Authors: | Yan Fei Liu Ke Long Huang Dong Ming Peng Su Qin Liu Hong Wu |
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| Institution: | Institute of Functional Materials and Chemistry, Central South University, Changsha 410083, China |
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| Abstract: | A new degradable aliphatic poly(butylene-co-e-caprolactone carbonate) (PBCL) was synthesized through the terpolymerization of carbon dioxide, 1,2-butylene oxide (BO) and e-caprolactone (CL), a polymer supported bimetallic complex (PBM) was used as a catalyst. The terpolymers prepared were characterized by FT-IR,1H NMR, 13C NMR, WXRD and DSC. The hydrolysis tests were carried out to appraise the degradability of the copolymers. |
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| Keywords: | Terpolymerization Aliphatic polycarbonate Degradability |
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