Synthesis of 2-epi-amphidinolide E: an unexpected and highly selective C(2)inversion during an esterification reaction |
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| Authors: | Va Porino Roush William R |
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| Institution: | Departments of Chemistry and Biochemistry, Scripps Florida, Jupiter, Florida 33458, USA. |
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| Abstract: | A synthesis of 2-epi-amphidinolide E (1) has been accomplished via an unexpected and highly diastereoselective C(2) stereochemical inversion during the modified Yamaguchi esterification of alcohol 4b and Fe(CO)3-complexed dienoic acid 7. reaction: see text]. |
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