Catalytic enantioselective allylation of ketones via a chiral indium(III) complex |
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| Authors: | Teo Yong-Chua Goh Joshua-Daniel Loh Teck-Peng |
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| Affiliation: | Department of Chemistry, 3 Science Drive, National University of Singapore, Singapore 117543. |
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| Abstract: | [reaction: see text] A chiral indium complex has been discovered to effect high enantioselectivities in the addition of allyltributylstannanes to ketones. The allylation of a variety of aromatic, alpha,beta-unsaturated and aliphatic ketones resulted in good yields and high enantioselectivities (up to 92% ee). |
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