Enhanced photoinduced oligomerization of fullerene via radical coupling between fullerene radical cation and radical anion using 9-mesityl-10-methylacridinium ion |
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Authors: | Ohkubo Kei Iwata Ryosuke Yanagimoto Takahiro Fukuzumi Shunichi |
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Institution: | Department of Material and Life Science, Graduate School of Engineering, Osaka University, SORST, Japan. |
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Abstract: | Photocatalytic oligomerization of fullerene in toluene-acetonitrile solution occurs efficiently via electron-transfer reactions with the photogenerated electron-transfer state of 9-mesityl-10-methylacridinium ion, followed by the radical coupling reaction between fullerene radical cation and radical anion. |
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