Blends of Polypropylene and Syndiotactic 1,2-Polybutadiene:Morphology,Crystallization Behaviors and Mechanical Properties |
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Authors: | ZHANG Cheng-wu HUANG Yu-dong WANG Sheng-chao ZHANG Chun-yu ZHANG Xue-quan |
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Institution: | ZHANG Cheng-wu 1,HUANG Yu-dong 1,WANG Sheng-chao 2,ZHANG Chun-yu3, ZHANG Xue-quan 3 1.Department of Applied Chemistry,Harbin Institute of Technology,Harbin 150001,P.R.China,2.Heilongjiang Provincial Plastics Industry Scientific Research Institute,3.Changchun Institute of Applied Chemistry,Chinese Academy of Sciences,Changchun 130022 |
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Abstract: | Morphologies,crystallization behavior and mechanical properties of polypropylene(PP)/syndiotactic 1,2-polybutadiene(s-1,2 PB) blends were investigated.Morphology observation shows the well dispersed domains of s-1,2 PB in PP matrix with the rather small domain sizes from 0.1 to 0.5 μm when the s-1,2 PB content increases from 5% to 20% (mass fraction) in the blends,and the phase structure tends to become co-continuous as s-1,2 PB content further increases.Crystallization temperature(Tc) of PP component in the blends is fluctuated with the variation of s-1,2 PB content in the blends.Compatibilization,to some extent,between the two components is inferred from the examination of both morphology and crystallization behavior.Improvement of impact strength of PP toughened by s-1,2PB becomes significant only in the case of s-1,2 PB content above 20%(mass fraction). |
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Keywords: | Syndiotactic 1 2-polybutadiene Polypropylene Crystallization SEM DSC |
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