Versatile dehydrogenative alcohol silylation catalyzed by Cu(I)-phosphine complex |
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| Authors: | Ito Hajime Watanabe Akiko Sawamura Masaya |
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| Affiliation: | Division of Chemistry, Graduate School of Science, Hokkaido University, Sapporo 060-0810, Japan. hajito@sci.hokudai.ac.jp |
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| Abstract: | [reaction: see text] Cu(I) complexes of xanthane-based diphosphines were versatile catalysts for dehydrogenative alcohol silylation, exhibiting high activity and broad substrate scope. Highly selective silylation of 1-decanol over 2-decanol is possible even with a silylating reagent of small steric demand such as HSiMe(2)Ph or HSiEt(3). |
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