Diarylprolinol silyl ether as catalyst of an exo-selective, enantioselective Diels-Alder reaction |
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| Authors: | Gotoh Hiroaki Hayashi Yujiro |
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| Institution: | Department of Industrial Chemistry, Faculty of Engineering, Tokyo University of Science, Kagurazaka, Shinjuku-ku, Tokyo 162-8601, Japan. |
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| Abstract: | In combined use with CF3CO2H, 2-bis(3,5-bis-trifluoromethylphenyl) triethylsiloxymethyl]pyrrolidine was found to be an effective organocatalyst of an exo-selective, enantioselective Diels-Alder reaction of alpha,beta-unsaturated aldehydes. |
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