Competitive binding of fluorosulfate anion in reactions of halogens and nitronium borofluoride with olefins |
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| Authors: | N. S. Zefirov A. S. Koz'min V. D. Sorokin V. V. Zhdankin Yu. N. Studnev A. V. Fokin |
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| Affiliation: | (1) M. V. Lomonosov Moscow State University, USSR;(2) A. N. Nesmeyanov Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, Moscow |
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| Abstract: | Conclusions Reactions of olefins with chlorine in the presence of fluorosulfonic acid salts lead to -chloroalkyl fluorosulfates together with 1,2-dichlorides. The addition of nitronium borofluoride to ethylene in the presence of tetraethylammonium fluorosulfate gives 2-nitroethyl fluorosulfate. These reactions confirm the general character of the competitive binding of superweak nucleophiles in AdE reactions.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 2, pp. 389–391, February, 1985. |
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