| 石英片基表面联吡啶钌配合物的合成与表征 |
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| 引用本文： | 赵剑英,马丽,金日哲,高连勋. 石英片基表面联吡啶钌配合物的合成与表征[J]. 高等学校化学学报, 2006, 27(12): 2337-2339 |
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| 作者姓名： | 赵剑英 马丽 金日哲 高连勋 |
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| 作者单位： | 1. 中国科学院长春应用化学研究所,高分子物理与化学国家重点实验室,长春,130022;中国科学院研究生院,北京,100049
2. 中国科学院长春应用化学研究所,高分子物理与化学国家重点实验室,长春,130022 |
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| 摘 要： | 将6-溴-2,2'∶6',2"-三联吡啶转化为6-甲酰基-2,2'∶6',2"-三联吡啶, 再将其与表面组装有氨基硅氧烷的石英片基反应, 使甲酰基与片基表面的氨基反应生成Schiff碱型化合物, 在氨基化片基表面成功地固定6-甲酰基-2,2'∶6',2"-三联吡啶及相应的钌配合物, 并用紫外-可见吸收光谱及光电子能谱(XPS)检测联吡啶及相应钌配合物的组装过程.
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| 关 键 词： | 自组装 联吡啶 钌配合物 Schiff碱 |
| 文章编号： | 0251-0790（2006）12-2337-03 |
| 收稿时间： | 2006-06-12 |
| 修稿时间： | 2006-06-12 |
Synthesis and Charaterization of Ru Complex with Terpyridine on Quartz Substrates Surface |
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| ZHAO Jian-Ying,MA Li,JIN Ri-Zhe,GAO Lian-Xun. Synthesis and Charaterization of Ru Complex with Terpyridine on Quartz Substrates Surface[J]. Chemical Research In Chinese Universities, 2006, 27(12): 2337-2339 |
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| Authors: | ZHAO Jian-Ying MA Li JIN Ri-Zhe GAO Lian-Xun |
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| Affiliation: | 1. State Key Laboratory of Polymer Physics and Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022, China; 2. Graduate School of Chinese Academy of Sciences , Beijing 100049, China |
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| Abstract: | The 6-carboxaldehyde-2, 2'∶6',2"-terpyridine was synthesized and assembled on the aminosilanization quartz substrate by the Schiff base interfacial group. Then the substrate was reacted with ruthenium and 6-bromo-2,2'-bipyridine to form a new Schiff base type Ru complexes. The process of the complexes assembled was characterized by UV-Vis absorption spectra and XPS. The film exhibited photoluminescence arising from π*-t2g ligand-to-metal transition of Ru complex. From the fluorescent spectra, we observed the behavior of Ru(Ⅱ) complexes is greatly affected by the schiff base ligand. The novel Schiff base ligand Ru(Ⅱ) complexes exhibited strong and pure luminescent intensity. It was different from the other type ruthenium complexes. The result shows that there are many ralations between the structure and the properties of the complex. |
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| Keywords: | Self-assemble Pyridine Ru complex Schiff base |
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