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A Facile Approach to Well-Dispersible CeO2 Nanoparticles
Authors:Jiaoxing Xu  Liping Li
Affiliation:State Key Structural Chemistry Laboratory , Fujian Institute of Research on the Structure of Matter, Graduate School of Chinese Academy of Science , Fujian, P. R. China
Abstract:18 nm CeO2 with surface being functionalized by nitrate groups were prepared to yield a stable suspension in acidic aqueous solution. Different from the bare ones, these suspensions precipitated rapidly when the solution became basic. Further tuning the solution back to acidic led to a stable suspension again. This phenomenon was explained in terms of the electrostatic repulsion of electrical double layers of intensive surface bound nitrate groups and acidic medium.
Keywords:CeO2  colloidal suspension  dispersibility  surface functionalization
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