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Dynamic Response Studies on Aggregation and Breakage Dynamics of Colloidal Dispersions in Stirred Tanks
Authors:M Soos  A S Moussa  L Ehrl  J Sefcik  H Wu  M Morbidelli
Institution:1. Institute for Chemical and Bioengineering, Department of Chemistry and Applied Bioscience , Zurich, Switzerland massimo.morbidelli@chem.ethz.ch;3. Institute for Chemical and Bioengineering, Department of Chemistry and Applied Bioscience , Zurich, Switzerland;4. Department of Chemical and Process Engineering , University of Strathclyde , Glasgow, Scotland, United Kingdom
Abstract:Aggregation and breakage of aggregates of fully destabilized polystyrene latex particles in turbulent flow was studied experimentally in both batch and continuous stirred tanks using small‐angle static light scattering. It was found that the steady‐state values of the root‐mean‐square radius of gyration are fully reversible upon changes of stirring speed as well as solid volume fraction. Steady‐state values of the root‐mean‐square radius of gyration were decreasing with decreasing solid volume fraction as well as with increasing stirring speed. Moreover, it was found that the steady‐state structure and shape of the aggregates is not influenced by the applied stirring speed.
Keywords:Root‐mean‐square radius of gyration  aggregation  breakage  steady-state reversibility  aggregate structure
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