Synthesis and Characterization of SnO2 Nanopowder Prepared by Precipitation Method |
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| Authors: | V. Senthilkumar M. Jayachandran C. Sanjeeviraja |
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| Affiliation: | 1. Department of Physics , Gandhigram Rural University , Gandhigram, India;2. Electrochemical Material Science Division, Central Electrochemical Research Institute , Karaikudi, India;3. Department of Physics , Alagappa University , Karaikudi, India |
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| Abstract: | Tetragonal SnO2 nanopowder of the range ～8 nm has been successfully synthesized by precipitation method. The prepared powder was characterized by thermogravimetry analysis (TGA), x-ray diffraction (XRD), transmission electron microscopy (TEM), Infrared spectroscopy (FTIR), x-ray photoelectron spectroscopy (XPS), diffuse reflectance spectroscopy (DRS), and room temperature photoluminescence (PL) spectroscopy. Experimental results show that the prepared powder was phase pure SnO2 of tetragonal rutile structure without any impurities. The optical band gap was determined to be 4.26 eV, using diffuse reflectance technique with the aid of Kubelka-Munk relation. The blue shift of the band gap was attributed to the quantum size confinement effect. |
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| Keywords: | Diffuse reflectance spectrum nanoparticle photoluminescence TEM tin oxide XPS |
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