Synthesis of Some Oil Spill Dispersants Based on Sorbitol Esters and Their Capability to Disperse Crude Oil on Seawater to Alleviate Its Accumulation and Environmental Impact |
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| Authors: | A. M. Al‐Sabagh Sabrnal H. El‐Hamouly Ayman M. Atta M. R. Noor El‐Din Moataz M. Gabr |
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| Affiliation: | 1. Egyptian Petroleum Research Institute , Cairo, Egypt alsabaghh@gmail.com;3. Faculty of Science, Chemistry Department , Menoufia University , Menoufia, Egypt;4. Egyptian Petroleum Research Institute , Cairo, Egypt;5. Qarun Petroleum Company , Cairo, Egypt |
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| Abstract: | In this respect mono‐, di‐, and tri‐ sorbitol oleate esters [SMO, SDO, and STO] were prepared and then ethoxylated using ethylene oxide to obtain six sorbitol esters at different ethylene oxide content (e.o=5, 12, 15, 20, 35, and 45). They were tested as oil spill dispersants individually and in blends. From the obtained data, it was found that the blends are more effective than the corresponding individual surfactants. The maximum dispersion capability for the prepared surfactants was obtained at HLB range from 9 to 11 for the both individual surfactants and blends. The increase of total carbon number in the surfactant alkyl group leads to increase dispersion capability of the dispersant. The wide range of ethylene oxide content was used, but the maximum dispersion efficiency was obtained at ethylene oxide=20 in E(20)STO. Meanwhile, the dispersion capability increases when the interfacial tension decreases. |
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| Keywords: | Oil spill dispersants oil spill dispersants surfactants alleviate oil spill |
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