Investigation Micellar Catalysis of p-Nitrophenyl Acetate Hydrolysis with Mn(Niten)2H2O Complex |
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Authors: | Hisham J Y El-Aila |
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Institution: | 1. Department of Chemistry , Al-Aqsa University, Gaza, Palestinain National Authority , via Israelheshamaila@yahoo.com |
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Abstract: | In this article, a mononuclear Mn(Niten)2H2O complex was prepared to catalyze hydrolysis of p-nitrophenyl acetate (PNPA) in presence of Cetyltrimethylammonium bromide (CTAB) micellar system in different pH range from 6.5–10 at 25°C. These results obtained indicate that the complex exhibits good catalytic function. It also appears the complex accelerates the hydrolytic cleavage of PNPA in cationic CTAB micellar solution which may be due to coordinating ability of substrate to complex, electrostatic interaction between micelles and complex and due to electrostatic interaction between micelles with reactant. |
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Keywords: | Hydrolysis kinetic treatment Mn(Niten)2H2O complex p-nitrophenyl acetate |
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