Esterification of Octanoic Acid with Octanol in Microemulsion and Emulsion System |
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Authors: | Li Fan Shengrong Yang |
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Institution: | 1. LanZhou Institute of Chemical Physics , Chinese Academy of Sciences , LanZhou, P. R. China;2. XinJiang Technical Institute of Physics and Chemistry , Chinese Academy of Sciences , Urumqi, P. R. China;3. Graduate University of the Chinese Academy of Sciences , Beijing, P. R. China;4. LanZhou Institute of Chemical Physics , Chinese Academy of Sciences , LanZhou, P. R. China |
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Abstract: | The esterification of octanoic acid with octanol in microemulsion and emulsion system is studied. In the presence of 5–10% dodecylbenzene-sulfonic acid (DBSA), which is a surfactant-type catalyst, high conversion of esterification can be given both in microemulsion and in emulsion system. Compared with emulsion system, single-phase microemulsion is a more effective reaction system for esterification, with the advantages of comparatively little influence by the amount of water, no need of hard stirring, and stable state when laid long. The esterification of other fatty acids and alcohols in this reaction system were also accomplished in favorable conversion. |
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Keywords: | Emulsion esterification DBSA microemulsion |
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