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Evaluation of Water-in-Crude-Oil Emulsion Stability Using Critical Electric Field: Effect of Emulsion Preparation Procedure and Crude Oil Properties
Authors:Raquel C C Coutinho  Jose Carlos Pinto  Marcio Nele  Andreas Hannisdal  Johan Sjöblom
Institution:1. Petrobras/Cenpes, Cidade Universitária , Rio de Janeiro, Brazil rcoutinho@petrobras.com.br;3. Programa de Engenharia Química/COPPE, Universidade Federal do Rio de Janeiro, Cidade Universitária , Rio de Janeiro, Brazil;4. Escola de Química-Universidade Federal do Rio de Janeiro, Cidade Universitária , Rio de Janeiro, Brazil;5. Aibel Technologies , Billingstad, Norway;6. Department of Chemical Engineering , Norwegian University of Science and Technology, Ugelstad Laboratory , Trondheim, Norway
Abstract:The critical electrical field has been used as a tool to probe water in crude emulsion stability to electrical fields in many previous studies. Given the increasing importance of this metric, this study investigates factors that are important to the reproducibility of the measurement and the effect of emulsion preparation variables on the critical electric field. It was observed that the emulsion preparation procedure has a strong effect on the measured critical electric field due to droplet size effects. Furthermore, the effect of crude oil properties on the critical electric field was investigated using emulsions from different oils but with the same average droplet diameter, where it was found that the measurement was dominated by crude oil viscosity.
Keywords:Critical electrical field  crude oil  electrocoalescence  emulsion stability  water-in-oil emulsion
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