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Effect of Hydrothermal on the Crystalline Phase and Morphology of Manganese Oxide Nanocrystals
Authors:Jin Mu  Zhenfang Gu  Zhiqing Zhang  Xiangqing Li  Shi‐Zhao Kang  Lei Wang
Institution:1. Department of Chemistry , East China University of Science and Technology , Shanghai, China jinmu@ecust.edu.cn;3. Department of Chemistry , East China University of Science and Technology , Shanghai, China
Abstract:The effect of hydrothermal on the crystalline phase and morphology of manganese oxide nanocrystals was studied. The Mn3O4 nanoparticles were transformed into γ‐MnOOH nanowires after hydrothermal treatment. The pH plays an important role in the transformation of crystalline phases. The whole nanowires of γ‐MnOOH were formed at pH 8 and pH 9 while the crystalline phase of Mn3O4 was still remained in the mixture of Mn3O4 and γ‐MnOOH at pH 10.
Keywords:Manganese oxides  nanocrystals  hydrothermal treatment  crystalline phases  morphology
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