Synthesis and Properties of a New Piperazine-Based Bicaudate Gemini Surfactant |
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Authors: | Sheng Zhong Lijing Gong Linlin Zhang |
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Institution: | 1. School of Chemical Engineering , University of Science and Technology Liaoning , Anshan , Liaoning , P. R. China shengzh-99@163.com;3. School of Chemical Engineering , University of Science and Technology Liaoning , Anshan , Liaoning , P. R. China |
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Abstract: | A novel bicaudate gemini surfactant was synthesized with anhydrous piperazine, chloride- bian, and 1-bromo dodecane as raw materials. Its structure was verified by infrared and 1H NMR. The surface active properties of the bicaudate gemini surfactant in water were measured at 55°C. Its critical micelle concentration (cmc) and γ cmc was 0.50 mmol · L?1 and 28.95 mN · m?1, respectively. Results indicate that there was not a remarkable difference in γcmc values between the synthesized bicaudate surfactant and conventional gemini surfactant N,N′–bis (dodecyl dimethyl ammonium bromide)-3-oxa-1,5-pentadiammonium. The sterilizing antimicrobial performance of the bicaudate gemini surfactant was examined. The bicaudate gemini surfactant show excellent inhibition against 18 types of bacteria compared with conventional monomeric surfactant and gemini surfactant at concentrations of 50 mg/L. |
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Keywords: | Bactericidal activities bicaudate gemini surfactant piperazine surface tension |
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