Preparation of L-Alanine Crystals Containing Gold Nanoparticles |
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Authors: | Masako Koyama Masaharu Shiraishi Koji Sasaki Kijiro Kon-no |
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Institution: | 1. Department of Industrial Chemistry , Faculty of Engineering, Tokyo University of Science , Shinjuku-ku , Tokyo , Japan;2. Bio-Industrialization Center, Bio-Products Department, Ajinomoto Co. , Kawasaki , Japan masako_koyama@ajinomoto.com;4. Department of Industrial Chemistry , Faculty of Engineering, Tokyo University of Science , Shinjuku-ku , Tokyo , Japan |
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Abstract: | Amino acids provide useful foods, medicines, health foods, and nutritional supplements. We studied the morphology control of alanine, an amino acid. We also studied the effects of amino acid addition on the dispersion stability of gold nanoparticles. We then studied hybridization between alanine crystals and arginine-capped gold nanoparticles. Alanine crystal growth in a supersaturated alanine solution was found to increase linearly over time, and alanine crystal growth stopped as supersaturation decreased. Alanine crystals with arginine grew toward the c-axis because arginine was adsorbed onto the face (120) of alanine crystals. Absorption wavelengths of colloidal solutions changed for gold nanoparticles with arginine, suggesting that arginine was adsorbed onto gold nanoparticles. The change in alanine crystal morphology was the same for alanine crystals with arginine-capped gold nanoparticles in that it grew toward the c-axis. Alanine crystals contained arginine-capped gold nanoparticles toward the c-axis. |
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Keywords: | Alanine crystal growth amino acids arginine-capped gold nanoparticles crystals containing nanoparticles morphology control |
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