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Two-stage latexes of polystyrene acrylates
Authors:Dan Donescu  Liana Fusulan  Stela Lungoci  Sever Serban  Cristian Peteu
Institution:1. Institute of Chemical Research 202 Splaiul Indepcndentei 77208 , PO Box 15-159, Bucharest 6, Romania;2. ROMACR1L , Rasnov, SA, Romania
Abstract:ABSTRACT

The modification of decomposition rate of the potassium persulfate initiator during the synthesis of “two-stage latexes” polystyrene-ethyl acrylate (EtA) of butyl acrylale (BuA) and of 2-ethylhexyl acrylate (EHA) is studied. This rate is minimum for BuA and maximum for EHA, in good agreement with the value of solubility parameters. The appearance of poryacrvlaf.es determines the existence of water bonded to the polar polymer. The amount of water bonded increases in the sequence PEtA?PBuA?PEHA, function of the modification of the diameters of the particles resulted from the latexes obtained.
Keywords:Aquapentacyanoferrate(II)  D-PA  ligand substitution  sodium dodecylsulphate  spectrophotometry
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