Selective and recyclable palladium porphyrins-catalyzed oligomerization of tert-butyl acetylene in environment-friendly ionic liquids |
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| Authors: | Jin-Sheng Cheng Guo-Feng Wei Jin Zhao Shi-Wen Huang Zu-Liang Huang |
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| Institution: | (1) School of Basic Medical Science, Youjiang Medical College for Nationalities, Baise, 533000, China;(2) Guangzhou Institute of Biomedicine and Health, Chinese Academy of Sciences, Guangzhou, 510650, China |
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| Abstract: | Efficient and selective palladium porphyrins-catalyzed olimerization of tert-butyl acetylene to form (3Z,5Z)-2,2,7,7-tetramethyl-3,6-dihalo-3,5-octadiene has been developed in environment-friendly ionic
liquids. The reaction proceeded readily with effective recycling of the ionic liquids and easy isolation of the products. |
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| Keywords: | Palladium porphyrins ionic liquids oligomerization environment friendly |
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