Tetraphenyloxybenziporphyrin, a new organometallic ligand for silver(III) and gold(III) |
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Authors: | El-Beck Jessica A Lash Timothy D |
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Affiliation: | Department of Chemistry, Illinois State University, Normal, Illinois 61790-4160, USA. |
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Abstract: | [Structure: see text] Reaction of 4-hydroxyisophthalaldehyde with excess phenyl magnesium bromide gave a dicarbinol and this condensed with pyrrole and aromatic aldehydes in the presence of BF3.Et2O to afford, following oxidation with DDQ, novel tetraarylcarbaporphyrinoids in 10-24% yield. Further reaction with silver(I) acetate or gold(III) acetate gave stable organometallic derivatives that retained the aromatic characteristics of the parent macrocycle. |
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