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| 丙烷氧化脱氢M-Fe-O催化剂的研究 | |
| 引用本文： | 徐爱菊,照日格图,林勤. 丙烷氧化脱氢M-Fe-O催化剂的研究[J]. 分子催化, 2007, 21(5): 447-452 |
| 作者姓名： | 徐爱菊 照日格图 林勤 |
| 作者单位： | 1. 北京科技大学,冶金与生态工程学院,北京,100083;内蒙古师范大学,化学与环境科学学院,内蒙古,呼和浩特,010022 2. 内蒙古师范大学,化学与环境科学学院,内蒙古,呼和浩特,010022 3. 北京科技大学,冶金与生态工程学院,北京,100083 |
| 基金项目： | 国家教育部科学技术研究重点项目204027，内蒙古师范大学青年基金资助项目(QN2005016) |
| 摘 要： | 采用微波加热草酸盐共沉淀法制备了一系列M-Fe-O(M=V、Cr、Mn、Co、Ni、Cu、Zn)催化剂,考察了其对丙烷氧化脱氢制丙烯反应的催化性能,并对催化剂进行了BET、XRD、H2-TPR、电导测量等表征.实验结果表明V-Fe-O和Cr-Fe-O催化剂表现出较好的丙烷氧化脱氢制丙烯催化性能.反应温度为873 K时,以V-Fe-O为催化剂时丙烷转化率34.46%,丙烯选择性30.91%;在Cr-Fe-O为催化剂上丙烷转化率36.31%,丙烯选择性34.22%. |
| 关 键 词： | M-Fe-O催化剂 丙烷 氧化脱氢 微波加热 |
| 文章编号： | 1001-3555（2007）05-0447-06 |
| 修稿时间： | 2006-11-09 |
Study on M-Fe-O Catalysts for Oxidative Dehydrogenation of Propane to Propene |
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| XU Ai-ju,ZHAORI GETU,LIN Qin. Study on M-Fe-O Catalysts for Oxidative Dehydrogenation of Propane to Propene[J]. Journal of Molecular Catalysis (China), 2007, 21(5): 447-452 | |
| Authors: | XU Ai-ju ZHAORI GETU LIN Qin |
| Abstract: | A series of M-Fe-O(M= V,Cr,Mn,Co,Ni,Cu,Zn) catalysts were prepared by oxalate co-precipitation method with microwave heating and characterized by X-ray diffraction(XRD),BET specific surface,H2-TPR and conductivity measurement.Their catalytic performance for the oxidative dehydrogenation of propane to propene had been investigated.It was found that the M-Fe-O(M=V,Cr) catalysts showed higher catalytic activity for propene formation.At 873 K,34.46% C3H8 conversion and 30.91% C3H6 selectivity over V-Fe-O catalyst,36.31% C3H8 conversion and 34.22% C3H6 selectivity over Cr-Fe-O catalyst were obtained respectively. |
| Keywords: | M-Fe-O catalyst propane oxidative dehydrogenation microwave heating |
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