Functional Methacryloyoxy Acetals: II. Electophilic Addition of Alcohols to Vinyloxyalkyl Methacrylates |
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| Authors: | O V Gorelova L A Oparina L N Parshina N K Gusarova B A Trofimov |
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| Institution: | (1) Siberian Division, Russian Academy of Sciences, Faworsky Irkutsk Institute of Chemistry, Irkutsk, 664033, Russia |
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| Abstract: | Alcohols of various structures, in particular, ethylene, acetylene, fluorocontaining alcohols, add regio- and chemoselectively to the vinyloxy group of vinyloxyalkyl methacrylates at 20-40°C in the presence of catalytic quantities of trifluoroacetic acid affording functional acetalmethacrylates in high yield. |
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