| 亚甲基[60]富勒烯羧酸的酯化 |
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| 引用本文： | 王乃兴. 亚甲基[60]富勒烯羧酸的酯化[J]. 合成化学, 2000, 8(5): 422-424 |
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| 作者姓名： | 王乃兴 |
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| 作者单位： | 克莱姆森大学化学系,南卡罗来纳,29634 |
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| 摘 要： | 将常用的有机催化剂如Ｎ，Ｎ′－二环乙基碳二亚胺、４－二甲氨基吡啶和１－羟基苯并三唑用于亚甲基「６０」富勒烯羧酸的经典酯化反应，没有得到所期待的哑铃形偶联物，而得到单亚甲基富勒烯乙基酯，用柱色谱分离的产物经ＭＡＬＰＩ和ＦＴ－ＩＲ证实，并提出可能的反应机理。
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| 关 键 词： | 亚甲基[60]富勒烯羧酸 酯化反应 机理 |
A Esterification of Methano[60]Fullerene Carboxylic Acid |
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| Abstract. A Esterification of Methano[60]Fullerene Carboxylic Acid[J]. Chinese Journal of Synthetic Chemistry, 2000, 8(5): 422-424 |
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| Authors: | Abstract |
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| Abstract: | Organic catalytic reagents such as N, N＇-dicyclohexylcarhodiimide, 4-dimethy-laminopyridine and 1-hydroxybenzotriazole were used for titled esterification which is a classicalorganic reaction, the expected dumbbell-shaped coupling compound was not got but obtained themono-methano [60] Fullerene ethyl carbonate. The product was isolated by columnchromatography and was indentified by MALDI-MS and FT-IR spectrum. A suggested reactionmechanism was given. |
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| Keywords: | Fullerene Carboxylic acid Esterification Synthesis Mechanism. |
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