Cobalt(iii) complexes as functional ligands for metal (oxide) surfaces |
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| Authors: | Rachel J Cooper Reuben T Jane Thomas E Jeffs Richard M Hartshorn Peter A Tasker |
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| Institution: | EaStCHEM School of Chemistry, The University of Edinburgh, EH9 3JJ, UK. p.a.tasker@ed.ac.uk. |
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| Abstract: | Co(iii) polyamine complexes with either two or three labile coordination sites bind strongly to high surface area metal oxides such as goethite or aluminium trihydroxide, and have been shown to act as passivating agents for aluminium flake in aqueous media, in addition to providing a potential method for surface functionalisation. |
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