Microstructural stability of the Kirkendall plane in solid-state diffusion |
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Authors: | van Dal M J Gusak A M Cserháti C Kodentsov A A van Loo F J |
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Institution: | Laboratory of Solid State and Materials Chemistry, Einghoven University of Technology, P.O. Box 513, 5600 MB Eindhoven, The Netherlands. |
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Abstract: | In a diffusion-controlled interaction, the Kirkendall plane, as marked by inert particles placed at the original contact surface of a reaction couple, need not be unique. Multiple planes can develop, and sometimes the Kirkendall plane does not exist at all. A phenomenological approach is introduced to rationalize the Kirkendall-effect-mediated migration of macroscopic inclusions inside a diffusion zone. |
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