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Microstructural stability of the Kirkendall plane in solid-state diffusion
Authors:van Dal M J  Gusak A M  Cserháti C  Kodentsov A A  van Loo F J
Institution:Laboratory of Solid State and Materials Chemistry, Einghoven University of Technology, P.O. Box 513, 5600 MB Eindhoven, The Netherlands.
Abstract:In a diffusion-controlled interaction, the Kirkendall plane, as marked by inert particles placed at the original contact surface of a reaction couple, need not be unique. Multiple planes can develop, and sometimes the Kirkendall plane does not exist at all. A phenomenological approach is introduced to rationalize the Kirkendall-effect-mediated migration of macroscopic inclusions inside a diffusion zone.
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