Some new cobalt(II) complexes: Synthesis,characterization and thermal studies |
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Authors: | Kumar D N Garg B S |
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Institution: | (1) Department of Chemistry, University of Delhi, Delhi, 110007, India |
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Abstract: | Cobalt(II) complexes of tetradentate Schiff bases of the type CoL H2L=C20H16N2O2 (H2dsp), C21H18N2O2 (H2dst), C20H15N3O4 (H2ndsp) and C16H16N2O2 (H2salen)] have been synthesized and characterized by UV-visible, IR, and magnetic studies. Various thermodynamic parameters have been calculated for the decomposition step using TG/DTA. C20H14N2O2Co complex has the minimum and C16H14N2O2Co complex has the maximum activation energy.This revised version was published online in November 2005 with corrections to the Cover Date. |
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Keywords: | cobalt(II) thermal studies Schiff base |
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