Preparation of some metal carbonyl cluster formyl compounds |
| |
| Authors: | Brian F.G. Johnson Raymond L. Kelly Jack Lewis John R. Thornback |
| |
| Affiliation: | University Chemical Laboratory, Lensfield Road, Cambridge CB2 1EW Great Britain |
| |
| Abstract: | The reduction of H2Os3(CO)10S or HOs3(CO)10(O2CMe) with KBH(OPr-i)3 at low temperatures yields unstable formyl complexes which have been identified by 1H NMR spectroscopy; at higher temperatures conversion into stable hydridoanions is observed. |
| |
| Keywords: | |
| 本文献已被 ScienceDirect 等数据库收录！ |
